ôô

Why Do Apples Turn Brown?

When you cut an apple, does it turn brown because it has started to rot, or is something else going on? Ask Science explains.

By
Lee Falin, PhD
3-minute read
Episode #13

The Catechol Two-Step

To understand just what this weapon does, let’s examine its name in reverse. The last word ends in “-ase,” which means this is an enzyme. An enzyme is a special type of protein that helps a reaction speed up. Since it is an “oxidase,” this means that the reaction will oxidize something.

You might remember that I mentioned oxidation in my Science of Fire episode. An oxidation reaction is one in which electrons are taken from something by an oxidizing agent, usually oxygen. In the case of catechol oxidase, that something is catechol. When the tissue of an apple is damaged, the catechol oxidase and catechol get mixed together. The result is a compound called ortho-quinone, an antiseptic that provides the fruit with a defence against bacteria and fungi.

When ortho-quinone reacts with oxygen, it forms a brown-coloured compound called melanin, the same substance that causes your skin to tan when it is exposed to sunlight. Just like sun exposure, a little browning of your apple won’t hurt you. However the longer this process goes on, the less nutritious the apple becomes.

Biochemical Cease Fire

If you’re particularly averse to brown fruit, there are a couple of things you can do to slow down this reaction. First, like most chemical reactions, this one can be slowed down by exposure to cold. That’s why apples stored in the refrigerator don’t brown as fast as those left out on the counter.

Second, like most enzymes, catechol-oxidase operates most efficiently in a certain pH range. If the pH level leaves this optimal range, the enzyme will start to lose its shape, a process called denaturation. Since the enzyme is what speeds up the reaction, this denaturation will cause the reaction to proceed more slowly. A simple way to change the pH is to spray the apples with some lemon juice. Since lemon juice is a strong acid, this lowers the pH enough to denature the enzymes that cause browning.

Finally, you can put the apple someplace where there is no oxygen, such as outer space, or in a vacuum sealed bag with an oxygen absorber pack.

Conclusion

Now you know the true story behind why apples turn brown. This process holds true for bananas and potatoes as well. If you’re interested in learning more, here’s a fun experiment you can do in your very own kitchen.

If you liked today’s episode, you can become a fan of Ask Science on Facebook or follow me on Twitter. If you have a question that you’d like to see on a future episode, send me an email at everydayeinstein@quickanddirtytips.com

Apple image courtesy of Shutterstock.

Pages

Please note that archive episodes of this podcast may include references to Ask Science. Rights of Albert Einstein are used with permission of The Hebrew University of Jerusalem. Represented exclusively by Greenlight.

About the Author

Lee Falin, PhD

Dr. Lee Falin earned a B.S. in Computer Science from the University of Illinois, then went on to obtain a Ph.D. in Genetics, Bioinformatics, and Computational Biology from Virginia Tech.